000201533 001__ 201533
000201533 005__ 20190317000003.0
000201533 0247_ $$2doi$$a10.1002/ange.201407144
000201533 02470 $$2ISI$$a000343751100026
000201533 037__ $$aARTICLE
000201533 245__ $$aSelf-Assembly of a Giant Molecular Solomon Link from 30 Subcomponents
000201533 269__ $$a2014
000201533 260__ $$bWiley-Blackwell$$c2014
000201533 336__ $$aJournal Articles
000201533 520__ $$aThe synthesis of topologically complex structures, such as links and knots, is one of the current challenges in supramolecular chemistry. The so-called Solomon link consists of two doubly interlocked rings. Despite being a rather simple link from a topological point of view, only few molecular versions of this link have been described so far. Here, we report the quantitative synthesis of a giant molecular Solomon link from 30 subcomponents. The highly charged structure is formed by assembly of 12 cis-blocked Pt2+ complexes, six Cu+ ions, and 12 rigid N-donor ligands. Each of the two interlocked rings is composed of six repeating Pt(ligand) units, while the six Cu+ ions connect the two rings. With a molecular weight of nearly 12kDa and a diameter of 44.2 angstrom, this complex is the largest non-DNA-based Solomon link described so far. Furthermore, it represents a molecular version of a stick link.
000201533 6531_ $$acopper
000201533 6531_ $$amolecular link
000201533 6531_ $$aplatinum
000201533 6531_ $$aself-assembly
000201533 6531_ $$atopology
000201533 700__ $$0242609$$g170415$$aSchouwey, Clément
000201533 700__ $$aHolstein, Julian J.
000201533 700__ $$0240189$$g148592$$aScopelliti, Rosario
000201533 700__ $$0245623$$g180919$$aZhurov, Konstantin O.
000201533 700__ $$0247393$$g235390$$aNagornov, Konstantin O.
000201533 700__ $$g174689$$aTsybin, Yury O.$$0240220
000201533 700__ $$aSmart, Oliver S.
000201533 700__ $$aBricogne, Gérard
000201533 700__ $$aSeverin, Kay$$g145138$$0240333
000201533 773__ $$j53$$tAngewandte Chemie International Edition$$k42$$q11261-11265
000201533 8564_ $$uhttps://infoscience.epfl.ch/record/201533/files/Angew-2014-Schouwey_1.pdf$$zn/a$$s921550$$yn/a
000201533 909C0 $$xU10109$$0252071$$pLCS
000201533 909C0 $$pLSMB$$xU11424$$0252074
000201533 909CO $$qGLOBAL_SET$$pSB$$particle$$ooai:infoscience.tind.io:201533
000201533 917Z8 $$x148577
000201533 917Z8 $$x145138
000201533 917Z8 $$x145138
000201533 917Z8 $$x145138
000201533 917Z8 $$x145138
000201533 917Z8 $$x148230
000201533 937__ $$aEPFL-ARTICLE-201533
000201533 973__ $$rREVIEWED$$sPUBLISHED$$aEPFL
000201533 980__ $$aARTICLE