Olefin Hydrogenation with Single-Site Gold

Butene hydrogenation activity is intimately connected with the occupied and unoccupied electronic states of gold active site. We prepare well-defined Au(III) sites in IRMOF-3 structure, and tuned the metal density-of-states by replacing the substituent group of the coordinating group at position 5. Resonant inelastic X-ray scattering experiments and theoretical calculations revealed an increase in unoccupied 5d states of Au when the substituent group is a donating group, which leads to a dramatic increase in catalytic activity.


Publié dans:
Acta Physica Polonica A, 125, 4, 940-943
Année
2014
Publisher:
Warsaw, Polish Academy of Sciences Warsaw
ISSN:
0587-4246
Laboratoires:




 Notice créée le 2014-08-29, modifiée le 2018-09-13


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