Reactions of Grignard Reagents with Nitrous Oxide

The chemical activation of nitrous oxide (N2O) can be achieved by organocalcium, organosodium, and organolithium compounds. Grignard reagents, on the other hand, are believed to be inert. We demonstrate that this generalization is not correct. Some aliphatic Grignard reagents undergo a rapid conversion when subjected to an atmosphere of N2O. Hydrazones are the main reaction products.


Publié dans:
Organometallics, 33, 10, 2405-2408
Année
2014
Publisher:
Washington, American Chemical Society
ISSN:
0276-7333
Laboratoires:




 Notice créée le 2014-08-29, modifiée le 2019-03-17

n/a:
Télécharger le document
PDF

Évaluer ce document:

Rate this document:
1
2
3
 
(Pas encore évalué)