Contributions to the Chemistry of the Cyclopentadienyl Complex [Cp^RuCl2](2) ("Cp-roof" = eta(5)-1-Methoxy-2,4-tert-butyl-3-neopentylcyclopentadienyl)
Risse, Julie; Dutta, Barnali; Solari, Euro; Scopelliti, Rosario; Severin, Kay
2014
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Abstract

The dimeric ruthenium complex [Cp^RuCl2](2) is easily accessible in a one-pot reaction from RuCl3(solv)(n) and tert-butylacetylene. It features sterically very demanding "Cp-roof" ligands (Cp^ = eta(5)-1-methoxy-2,4-tert-butyl-3-neopentylcyclopentadienyl), which impart a unique reactivity. Herein we describe the synthesis and the characterization of novel Cp boolean AND Ru complexes bearing a bridging carbene ligand, a linear imido ligand, or an orthometalated phosphine ligand. Furthermore, the microwave-assisted syntheses of the bimetallic complexes [Cp^Ru(mu-Cl)(3)Ru(p-cymene)] and [Cp^Ru(mu-Cl)(3)RhCp*] are described.

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Title Contributions to the Chemistry of the Cyclopentadienyl Complex [Cp^RuCl2](2) ("Cp-roof" = eta(5)-1-Methoxy-2,4-tert-butyl-3-neopentylcyclopentadienyl)
Author(s) Risse, Julie ; Dutta, Barnali ; Solari, Euro ; Scopelliti, Rosario ; Severin, Kay
Published in Zeitschrift fur Anorganische und Allgemeine Chemie
Pagination 8
Volume 640
Issue 7
Pages 1322-1329
Date 2014
Publisher Weinheim, Wiley-Blackwell
ISSN 0044-2313
Keywords
DOI https://doi.org/10.1002/zaac.201400048
Other identifier(s) View record in Web of Science
Laboratories LCS
Record Appears in Scientific production and competences > SB - School of Basic Sciences > ISIC - Institute of Chemical Sciences and Engineering > LCS - Laboratory of Supramolecular Chemistry
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Record creation date 2014-08-29

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