Scanning electrochemical microscopy determination of hydrogen flux at liquid|liquid interface with potentiometric probe

Scanning electrochemical microscopy potentiometric determination of local hydrogen concentration and its flux next to the liquid|liquid interface was demonstrated. This method is based on the shift of open circuit potential of Pt-based reversible hydrogen electrode. The detection system was verified with a system generating hydrogen under galvanostatic conditions. Then, it was applied to aqueous|1,2-dichloroethane interface where hydrogen is produced with decamethylferrocene as electron donor.


Published in:
Electrochemistry Communications, 43, 22-24
Year:
2014
Publisher:
New York, Elsevier
ISSN:
1388-2481
Keywords:
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 Record created 2014-03-19, last modified 2018-09-13

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