Photoreduction of CO2 Using [Ru(bpy)2(CO)L]n+ Catalysts in Biphasic Solution/Supercritical CO2 Systems
Voyame, Patrick; Toghill, Kathryn E.; Méndez, Manuel A.; Girault, Hubert H.
2013
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Abstract

The photosensitized reduction of carbon dioxide by the molecular catalyst [Ru(bpy)2(CO)L] is studied in a biphasic liquid-condensed gas system. Increasing pressure is shown to enhance the initial production rate and turnover number of the catalyst before deactivation of the system, especially for formation of carbon monoxide.

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Title Photoreduction of CO2 Using [Ru(bpy)2(CO)L]n+ Catalysts in Biphasic Solution/Supercritical CO2 Systems
Author(s) Voyame, Patrick ; Toghill, Kathryn E. ; Méndez, Manuel A. ; Girault, Hubert H.
Published in Inorganic Chemistry
Pagination 9
Volume 52
Issue 19
Pages 10949-10957
Date 2013
Publisher Washington, Amer Chemical Soc
ISSN 1520-510X
DOI https://doi.org/10.1021/ic401031j
Other identifier(s) View record in Web of Science
Laboratories LEPA
Record Appears in Scientific production and competences > SB - School of Basic Sciences > ISIC - Institute of Chemical Sciences and Engineering > LEPA - Laboratory of Physical and Analytical Electrochemistry
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Record creation date 2013-10-19

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