Photoreduction of CO2 Using [Ru(bpy)2(CO)L]n+ Catalysts in Biphasic Solution/Supercritical CO2 Systems

The photosensitized reduction of carbon dioxide by the molecular catalyst [Ru(bpy)2(CO)L] is studied in a biphasic liquid-condensed gas system. Increasing pressure is shown to enhance the initial production rate and turnover number of the catalyst before deactivation of the system, especially for formation of carbon monoxide.


Published in:
Inorganic Chemistry, 52, 19, 10949-10957
Year:
2013
Publisher:
Washington, Amer Chemical Soc
ISSN:
1520-510X
Laboratories:




 Record created 2013-10-19, last modified 2018-03-17

Publisher's version:
Download fulltextPDF
Supporting Information:
Download fulltextPDF
TOC graphic:
Download fulltextGIF
Rate this document:

Rate this document:
1
2
3
 
(Not yet reviewed)