Direct, in situ determination of pH and solute concentrations in formic acid dehydrogenation and CO2 hydrogenation in pressurised aqueous solutions using 1H and 13C NMR spectroscopy
Moret, Séverine; Dyson, Paul J.; Laurenczy, Gábor
2013

Abstract

In water, spin–lattice relaxation times (T1) and calibration curves for chemical shifts have been determined for the 13C and the 1H (C) atoms in HCOOH, HCOONa, CO2, Na2CO3 and NaHCO3 by NMR spectroscopy. These data facilitate kinetic and mechanistic studies for H2 storage/delivery in the carbon dioxide–formic acid systems under H2 and CO2 pressures.

Details

Title Direct, in situ determination of pH and solute concentrations in formic acid dehydrogenation and CO2 hydrogenation in pressurised aqueous solutions using 1H and 13C NMR spectroscopy
Author(s) Moret, Séverine ; Dyson, Paul J. ; Laurenczy, Gábor
Published in Dalton Transactions
Pagination 4
Volume 42
Pages 4353-4356
Date 2013
Publisher Cambridge, Royal Soc Chemistry
ISSN 1477-9234
Keywords
DOI https://doi.org/10.1039/c3dt00081h
Other identifier(s) View record in Web of Science
Laboratories LCOM
Record Appears in Scientific production and competences > SB - School of Basic Sciences > ISIC - Institute of Chemical Sciences and Engineering > LCOM - Laboratory of Organometallic and Medicinal Chemistry
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Record creation date 2013-03-06

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