TY - EJOUR DO - 10.1016/j.ica.2012.07.026 AB - Cationic bis-cyclometalated iridium(III) complexes [(C boolean AND N)(2)Ir(N boolean AND N)](PF6) with 2-(2'-pyridyl)-5-R-1,3,4-oxadiazoles (N boolean AND N; R = 1-adamantyl, mesityl, N-diphenylamino) have a redox gap of 2.58-2.68 V and exhibit orange-red phosphorescence in argon-saturated dichloromethane solution with a maximum, quantum yield, and excited-state lifetime of 613-644 nm, 2-6%, and 90-280 ns. (C) 2012 Elsevier B. V. All rights reserved. T1 - Phosphorescence of iridium(III) complexes with 2-(2-pyridyl)-1,3,4-oxadiazoles DA - 2013 AU - Shavaleev, Nail M. AU - Scopelliti, Rosario AU - Graetzel, Michael AU - Nazeeruddin, Mohammad K. JF - Inorganica Chimica Acta SP - 295-299 VL - 394 EP - 295-299 PB - Elsevier PP - Lausanne ID - 184040 KW - Iridium KW - 1 KW - 3 KW - 4-Oxadiazole KW - Ligand KW - Complex KW - Cyclometalation KW - Phosphorescence SN - 0020-1693 ER -