Slow fluorescence and fast intersystem crossing - The xanthone anomaly

Heinz, B.; Schmidt, B.; Root, C.; Milota, F.; Fierz, B.; Kiefhaber, T.; Zinth, W.; Gilch, P.

doi:10.1007/978-3-540-68781-8_166

Heinz, B.; Schmidt, B.; Root, C.; Milota, F.; Fierz, B.; Kiefhaber, T.; Zinth, W.; Gilch, P.

2007

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Abstract

Intersystem crossing of xanthone in protic solvents proceeds within ∼ 1 ps, whereas its fluorescence decays within 60–600 ps. This is due to a delayed fluorescence from a 3 nπ* state energetically close to the 1 ππ* state.

Details

Title Slow fluorescence and fast intersystem crossing - The xanthone anomaly

Author(s) Heinz, B. ; Schmidt, B. ; Root, C. ; Milota, F. ; Fierz, B. ; Kiefhaber, T. ; Zinth, W. ; Gilch, P.

Published in Ultrafast Phenomena XV

Editor(s)

Corkum, Paul ; Jonas, David M. ; Miller, R. J. Dwayne ; Weiner, Andrew M.

Series Springer Series in Chemical Physics, 88

Pages 513-515

Date 2007

Publisher Berlin, Springer

ISBN 3-540-68779-3

DOI https://doi.org/10.1007/978-3-540-68781-8_166

Laboratories LCBM

Record Appears in Scientific production and competences > SB - School of Basic Sciences > ISIC - Institute of Chemical Sciences and Engineering > LCBM - Fondation Sandoz Chair in Biophysical Chemistry of Macromolecules
Work outside EPFL
Book chapters
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Record creation date 2012-10-15