Relative carbanion basicities as driving force for an intramolecular silyl migration of lithiated biphenyls
Bonnafoux, Laurence; Scopelliti, Rosario; Leroux, Frederic R.; Colobert, Francoise
2007

Abstract

A solvent-dependent silyl migration of lithiated biphenyls is described, involving the intermediate formation of a pentacoordinated silicate complex. Differences in the relative basicities of the aryllithium intermediates are the possible driving force for this migration. (c) 2007 Elsevier Ltd. All rights reserved.

Details

Title Relative carbanion basicities as driving force for an intramolecular silyl migration of lithiated biphenyls
Author(s) Bonnafoux, Laurence ; Scopelliti, Rosario ; Leroux, Frederic R. ; Colobert, Francoise
Published in Tetrahedron Letters
Volume 48
Pages 8768-8772
Date 2007
Keywords
DOI https://doi.org/10.1016/j.tetlet.2007.10.004
Other identifier(s) View record in Web of Science
Laboratories ISIC-GE
Record Appears in Scientific production and competences > SB - School of Basic Sciences > ISIC - Institute of Chemical Sciences and Engineering > ISIC-GE - Institute of Chemical Sciences and Engineering
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Record creation date 2012-07-04