Charged cyclometalated iridium(III) complexes that have large electrochemical gap

Bis-cyclometalated cationic Ir(III) diimine complexes [Ir((CN)-N-Lambda)2((NN)-N-Lambda)](PF6) with 1-phenylpyrazoles ((CN)-N-Lambda) and 1-(4'-tert-butyl-2'-pyridyl) pyrazole ((NN)-N-Lambda) are white solids that have absorption onset below 425 nm and electrochemical gap of up to 3.5 V. (C) 2011 Elsevier B. V. All rights reserved.


Published in:
Inorganica Chimica Acta, 383, 316-319
Year:
2012
Publisher:
Elsevier
ISSN:
0020-1693
Keywords:
Laboratories:




 Record created 2012-03-22, last modified 2018-09-13


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