In situ time-resolved DXAFS study of Rh nanoparticle formation mechanism in ethylene glycol at elevated temperature
Asakura, Hiroyuki; Teramura, Kentaro; Shishido, Tetsuya; Tanaka, Tsunehiro; Yan, Ning; Xiao, Chaoxian; Yao, Siyu; Kou, Yuan
2012

Abstract

A combination of in situ time-resolved DXAFS and ICP-MS techniques reveals that the formation process of Rh nanoparticles (NPs) from rhodium trichloride trihydrate (RhCl3 center dot 3H(2)O) in ethylene glycol with polyvinylpyrrolidone (PVP) at elevated temperature is a first-order reaction, which indicates that uniform size Rh NPs appear consecutively and these Rh NPs do not aggregate with each other.

Details

Title In situ time-resolved DXAFS study of Rh nanoparticle formation mechanism in ethylene glycol at elevated temperature
Author(s) Asakura, Hiroyuki ; Teramura, Kentaro ; Shishido, Tetsuya ; Tanaka, Tsunehiro ; Yan, Ning ; Xiao, Chaoxian ; Yao, Siyu ; Kou, Yuan
Published in Physical Chemistry Chemical Physics
Volume 14
Pages 2983-2990
Date 2012
Keywords
DOI https://doi.org/10.1039/c2cp23070d
Other identifier(s) View record in Web of Science
Laboratories LCOM
Record Appears in Scientific production and competences > SB - School of Basic Sciences > ISIC - Institute of Chemical Sciences and Engineering > LCOM - Laboratory of Organometallic and Medicinal Chemistry
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Record creation date 2012-03-08

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