Controlling the formation of metallosupramolecular assemblies by metal ionic radii

The formation of either dinuclear double-stranded or pentanuclear circular helicates from a ligand containing two tridentate domains separated by a phenylene unit can be controlled by inter-ligand steric interactions which themselves are governed by the size of the metal ion.


Published in:
Chemical Communications, 46, 3496-3498
Year:
2010
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 Record created 2011-12-16, last modified 2018-03-17

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