A Synthetic Entry into the Taiwaniaquinoids Based on a Biogenetic Hypothesis: Total Synthesis of (-)-Taiwaniaquinone H
2010
Abstract
(Chemical Equation Presented) Less carbon: Following a biogenetic proposal, the unusual 6-5-6 carbon skeleton of C19 taiwaniaquinoids was obtained by an intramolecular benzilic acid rearrangement from a C20 precur-sor. A protecting-group-free total synthesis then allowed for the preparation of (-)-taiwaniaquinone H (see scheme). © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Details
Title
A Synthetic Entry into the Taiwaniaquinoids Based on a Biogenetic Hypothesis: Total Synthesis of (-)-Taiwaniaquinone H
Author(s)
Jana, Chandan Kumar ; Scopelliti, Rosario ; Gademann, Karl
Published in
Chemistry-A European Journal
Volume
16
Pages
7692-7695
Date
2010
Keywords
Other identifier(s)
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Laboratories
LSYNC
Record Appears in
Scientific production and competences > SB - School of Basic Sciences > SB Archives > LSYNC - Chemical Synthesis Laboratory
Peer-reviewed publications
Work produced at EPFL
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Published
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Record creation date
2011-12-16