[(Methylcarbamothioyl)disulfanyl]methyl N-methylcarbamodithioate

The title compound, C5H10N2S5, was unintentionally obtained as the product of an attempted synthesis of a methyl-carbamodithioic acid using methylamine and carbon disulfide. In the molecule, two dithiocarbamate groups are bridged by a -CH2S- unit. The C-S-S-C torsion angle is -90.13 (11)degrees. The crystal structure is stabilized by N-H center dot center dot center dot S interactions between neighbouring molecules. An intramolecular N-H center dot center dot center dot S hydrogen bond also occurs.


Published in:
Acta Crystallographica Section E-Structure Reports Online, 66, O2671-U1458
Year:
2010
Laboratories:




 Record created 2011-12-16, last modified 2018-01-28


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