Highly selective additions of hydride and organolithium nucleophiles to helical carbenium ions

Unsymmetrical cationic [4] helicenes react with hydride or organolithium reagents and the two diastereotopic faces can be discriminated with high efficiency (dr up to and higher than 49 : 1)


Published in:
Chemical Science, 2, 425-428
Year:
2011
Keywords:
Laboratories:




 Record created 2011-12-16, last modified 2018-01-28


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