Magnetic properties of the antiferromagnetic spin-1/2 chain system beta-TeVO4

The magnetic susceptibility and magnetization of high-quality single-crystal beta-TeVO4 are reported. We show that this compound, made of weakly coupled infinite chains of VO5 pyramids sharing corners, behaves as an S = 1/2 one-dimensional Heisenberg antiferromagnet. From magnetic experiments, we deduce the intrachain antiferromagnetic coupling constant, J/k(B) = 21.4 +/- 0.2 K. Below 5 K, a series of three phase transitions at 2.26, 3.28, and 4.65 K is observed.


Published in:
Physical Review B, 84, -
Year:
2011
Keywords:
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 Record created 2011-12-16, last modified 2018-01-28


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