Cross coupling of non-activated alkyl halides with alkynyl Grignard reagents catalyzed by a well-defined Ni pincer complex
Vechorkin, Oleg; Godinat, Aurélien; Scopelliti, Rosario; Hu, Xile
2011

Abstract

The nickel pincer complex 1 catalyzes the cross-coupling of the title compounds with remarkable substrate scope and functional group tolerance. A nickel/alkynyl species was isolated and shown to be catalytically competent. THF=tetrahydrofuran, O-TMEDA=bis[2-(N,N-dimethylaminoethyl)] ether.

Details

Title Cross coupling of non-activated alkyl halides with alkynyl Grignard reagents catalyzed by a well-defined Ni pincer complex
Author(s) Vechorkin, Oleg ; Godinat, Aurélien ; Scopelliti, Rosario ; Hu, Xile
Published in Angewandte Chemie International Edition
Volume 50
Issue 49
Pages 11777-11781
Date 2011
Keywords
Language English
DOI https://doi.org/10.1002/anie.201105964
Other identifier(s) View record in Web of Science
Laboratories LSCI
Record Appears in Scientific production and competences > SB - School of Basic Sciences > ISIC - Institute of Chemical Sciences and Engineering > LSCI - Laboratory of Inorganic Synthesis and Catalysis
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Record creation date 2011-09-24