Homo-Brook route to benzazocenols and congeners via allylsilane-derived aziridines

We describe a concise entry to benzazocenols intermediates, e.g. I, for mitomycinoids via a homo-Brook rearrangement-ring opening sequence of a silylated aziridine, e.g. II. The latter is obtained by intramol. 1,3-dipolar cycloaddn. of an azide with an allylsilane, followed by irradn. of the resulting triazoline.


Published in:
Tetrahedron Letters, 42, 9175-9178
Year:
2001
Publisher:
Elsevier Science Ltd.
ISSN:
0040-4039
Keywords:
Note:
CAPLUS AN 2001:905526(Journal)
Laboratories:




 Record created 2011-08-17, last modified 2018-09-13


Rate this document:

Rate this document:
1
2
3
 
(Not yet reviewed)