Enantioselective Palladium-Catalyzed Direct Arylations at Ambient Temperature: Access to Indanes with Quaternary Stereocenters

Albicker, Martin R.; Cramer, Nicolai

doi:10.1002/anie.200905060

Albicker, Martin R.; Cramer, Nicolai

2009

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Abstract

Pd-catalyzed enantioselective intramol. direct arylation of vinyl triflates using tailored TADDOL-based phosphoramidite ligands provides indanes, e.g. I, with quaternary stereocenters.

Details

Title Enantioselective Palladium-Catalyzed Direct Arylations at Ambient Temperature: Access to Indanes with Quaternary Stereocenters

Author(s) Albicker, Martin R. ; Cramer, Nicolai

Published in Angewandte Chemie, International Edition

Volume 48

Pages 9139-9142

Date 2009

Publisher Wiley-VCH Verlag GmbH & Co. KGaA

ISSN 1433-7851

Keywords

vinyl triflate palladium catalyst intramol stereoselective arylation; indane stereoselective prepn

Note CAPLUS AN 2009:1422738(Journal)

DOI https://doi.org/10.1002/anie.200905060

Laboratories LCSA

Record Appears in Scientific production and competences > SB - School of Basic Sciences > ISIC - Institute of Chemical Sciences and Engineering > LCSA - Laboratory of Asymmetric Catalysis and Synthesis
Peer-reviewed publications
Work outside EPFL
Journal Articles
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Record creation date 2011-08-17