Enantioselective Palladium-Catalyzed Direct Arylations at Ambient Temperature: Access to Indanes with Quaternary Stereocenters

• Published in: Angewandte Chemie, International Edition (ISSN: 1433-7851), vol. 48, p. 9139-9142, S9139/1-S9139/33
• Wiley-VCH Verlag GmbH & Co. KGaA, 2009

Pd-catalyzed enantioselective intramol. direct arylation of vinyl triflates using tailored TADDOL-based phosphoramidite ligands provides indanes, e.g. I, with quaternary stereocenters.

Keywords: vinyl triflate palladium catalyst intramol stereoselective arylation ; indane stereoselective prepn

Note:

CAPLUS AN 2009:1422738(Journal)

Reference

• EPFL-ARTICLE-168129
• doi:10.1002/anie.200905060

Record created on 2011-08-17, modified on 2017-05-12