Pd-catalyzed enantioselective intramol. direct arylation of vinyl triflates using tailored TADDOL-based phosphoramidite ligands provides indanes, e.g. I, with quaternary stereocenters.
Title
Enantioselective Palladium-Catalyzed Direct Arylations at Ambient Temperature: Access to Indanes with Quaternary Stereocenters
Published in
Angewandte Chemie, International Edition
Volume
48
Pages
9139-9142, S9139/1-S9139/33
Date
2009
Publisher
Wiley-VCH Verlag GmbH & Co. KGaA
ISSN
1433-7851
Note
CAPLUS AN 2009:1422738(Journal)