Relationship Between Structure and Solubility of Thiol-Protected Silver Nanoparticles and Assemblies

Relationship Between Structure and Solubility of Thiol-Protected Silver Nanoparticles and Assemblies

Bauer, Christina A.; Stellacci, Francesco; Perry, Joseph W.

2008

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Abstract

The solubility of alkylthiol-coated silver nanoparticles and the energetics of the ligand disordering have been investigated. Calorimetry measurements have provided correlations between the nature of the ligands and the enthalpy of the ligand disordering, which have guided the improvement of nanoparticle solubility and dispersion in organic media.

Details

Title Relationship Between Structure and Solubility of Thiol-Protected Silver Nanoparticles and Assemblies

Author(s) Bauer, Christina A. ; Stellacci, Francesco ; Perry, Joseph W.

Published in Topics in Catalysis

Volume 47

Issue 1-2

Pages 32-41

Date 2008

ISSN 1572-9028

Keywords

metal nanoparticles; silver nanoparticles; ligand-coated nanoparticles; order-disorder transition; nanoparticle solubility; nanoparticle assemblies

DOI https://doi.org/10.1007/s11244-007-9032-5

Laboratories SUNMIL

Record Appears in Scientific production and competences > STI - School of Engineering > IMX - Institute of Materials > SUNMIL - Supramolecular Nanomaterials and Interfaces Laboratory
Peer-reviewed publications
Work outside EPFL
Journal Articles
Published

Record creation date 2011-06-06