Sequential ATRA-Reductive Cyclopropanation Reactions with a Ruthenium Catalyst in the Presence of Manganese
Fernandez-Zumel, Mariano Alfonso; Buron, Charlotte; Severin, Kay
2011

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Abstract

Atom-transfer radical addition (ATRA) reactions of ethyl trichloroacetate, dichloromalononitrile, or diethyl 2,2-dichloromalonate with olefins followed by dechlorination have provided functionalized cyclopropanes in one step. The RuIII complex [Cp*RuCl2(PPh3)] was used as a catalyst precursor and commercial Mn powder as reducing agent. Reactions with the less activated substrate ethyl dichloroacetate gave ATRA products with high turnover numbers but cyclopropanation was not observed.

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Title Sequential ATRA-Reductive Cyclopropanation Reactions with a Ruthenium Catalyst in the Presence of Manganese
Author(s) Fernandez-Zumel, Mariano Alfonso ; Buron, Charlotte ; Severin, Kay
Published in European Journal of Organic Chemistry
Pages 2272-2277
Date 2011
Publisher Wiley-Blackwell
ISSN 1434-193X
Keywords
DOI https://doi.org/10.1002/ejoc.201100175
Other identifier(s) View record in Web of Science
Laboratories LCS
Record Appears in Scientific production and competences > SB - School of Basic Sciences > ISIC - Institute of Chemical Sciences and Engineering > LCS - Laboratory of Supramolecular Chemistry
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Record creation date 2011-03-10

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