Photodissociation of iodine complexes in relation to the cage effect
The photodissocn. I2M + hn -> I2 + M was studied for M = C2H6 and M = (C2H5)2O with excitation above the dissocn. limit of I2B state. Vibrational population distributions of the I2(B) product mols. are reported. The results are compared to previous studies of the dissocn. of similar I complexes and to studies of the cage effect in high d. gases and liqs.
Copyright 2003 ACS
Radiation Chemistry, Photochemistry, and Photographic and Other Reprographic Processes
Lab. Chim. Tech.,Ec. Polytech. Fed. Lausanne,Lausanne,Switz. FIELD URL:
written in English.
Cage effect (in photodissocn. of iodine complexes with ethane and Et ether); Photolysis (of iodine complexes, cage effect in); Energy level excitation (vibrational, in photodissocn. of iodine complexes)
Record created on 2011-02-01, modified on 2016-08-09