Photodissociation of iodine complexes in relation to the cage effect

The photodissocn. I2M + hn -> I2 + M was studied for M = C2H6 and M = (C2H5)2O with excitation above the dissocn. limit of I2B state. Vibrational population distributions of the I2(B) product mols. are reported. The results are compared to previous studies of the dissocn. of similar I complexes and to studies of the cage effect in high d. gases and liqs.


Published in:
Journal of Chemical Physics, 93
Year:
1990
Keywords:
Note:
Copyright 2003 ACS
CAPLUS
AN 1991:91724
CAN 114:91724
74-1
Radiation Chemistry, Photochemistry, and Photographic and Other Reprographic Processes
Lab. Chim. Tech.,Ec. Polytech. Fed. Lausanne,Lausanne,Switz. FIELD URL:
Journal
JCPSA6
written in English.
Cage effect (in photodissocn. of iodine complexes with ethane and Et ether); Photolysis (of iodine complexes, cage effect in); Energy level excitation (vibrational, in photodissocn. of iodine complexes)
Laboratories:




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