000162818 001__ 162818
000162818 005__ 20190723164947.0
000162818 0247_ $$2doi$$a10.1021/j100294a020
000162818 037__ $$aARTICLE
000162818 245__ $$aProduct vibrational state distributions in the photodissociation of iodine - rare gas clusters
000162818 269__ $$a1987
000162818 260__ $$c1987
000162818 336__ $$aJournal Articles
000162818 500__ $$aCopyright 2003 ACS
000162818 500__ $$aCAPLUS
000162818 500__ $$aAN 1987:186219
000162818 500__ $$aCAN 106:186219
000162818 500__ $$a74-1
000162818 500__ $$aRadiation Chemistry, Photochemistry, and Photographic and Other Reprographic Processes
000162818 500__ $$aLab. Chim. Tech.,Ec. Polytech. Fed. Lausanne,Lausanne,Switz. FIELD URL:
000162818 500__ $$aJournal
000162818 500__ $$aJPCHAX
000162818 500__ $$awritten in English.
000162818 500__ $$aPhotolysis (of iodine-rare gas clusters, product vibrational state distributions in); Helium-group gases Role: USES (Uses) (van der Waals compds. with iodine, photolysis of, product vibrational state distributions in); Energy level (vibrational, in products of dissocn. of iodine-rare gas clusters)
000162818 520__ $$aThe photodissocn. of I2M van der Waals clusters is studied at several wavelengths above the B state dissocn. limit with M = Ne, Ar, Kr, and Xe. The I2 product vibrational state distributions are obtained by measuring the dispersed B -> X fluorescence and analyzing the resulting spectra; excitation above the B state dissocn. limit leads to significantly different reaction dynamics compared to excitation of the bound levels of the B state studied previously. Among others the recoil energies of the I2 and M fragments are much larger, and the distributions of rovibrational states in the I2 product are much wider in the present expts. The relative translational energy in the I2* and M photodissocn. products is significantly larger than predicted by recent quasi-classical trajectory calcns. The fragment recoil energy does not vary strongly with the excitation wavelength.
000162818 6531_ $$a7439-90-9; 7440-01-9 (Neon); 7440-37-1 (Argon); 7440-63-3 Role: RCT (Reactant)
000162818 6531_ $$aRACT (Reactant or reagent) (photodissocn. of van der Waals complex of
000162818 6531_ $$awith iodine
000162818 6531_ $$aproduct vibrational state distributions in); 7553-56-2 (Iodine) Role: RCT (Reactant)
000162818 6531_ $$aRA
000162818 6531_ $$aphotodissocn van der Waals cluster; iodine rare gas cluster photolysis; vibrational state distribution cluster photolysis; complex van der Waals photodissocn
000162818 700__ $$aPhilippoz, J. M.
000162818 700__ $$0240886$$g106613$$aVan den Bergh, H.
000162818 700__ $$aMonot, R.
000162818 773__ $$k10$$j91$$tJournal of physical Chemistry$$q2545-2550
000162818 909CO $$particle$$ooai:infoscience.tind.io:162818
000162818 909C0 $$pLPAS$$0252376$$xU10271
000162818 937__ $$aEPFL-ARTICLE-162818
000162818 973__ $$rREVIEWED$$sPUBLISHED$$aEPFL
000162818 980__ $$aARTICLE