Infrared vibrational predissociation of van der Waals clusters: applications to isotope separation

Isotope sepn. was demonstrated following the selective IR laser-induced photodissocn. of van der Waals clusters in a free jet. Irradn. of a natural abundance mixt. of SF6 isotopomers dild. in Ar with a 20-W cw CO2 laser gave overall enrichment factors >1.1. By adjusting the wavelength one can either enrich or deplete the center of the free jet in any one of the S isotopes.


Published in:
Journal of Physical Chemistry, 88, 18, 3936–3938
Year:
1984
Keywords:
Note:
Copyright 2003 ACS
CAPLUS
AN 1984:499644
CAN 101:99644
71-6
Nuclear Technology
74
Inst. Chim. Phys.,Ec. Polytech. Fed. Lausanne,Lausanne,Switz. FIELD URL:
Journal
JPCHAX
written in English.
Isotope separation (of sulfur, IR laser photodissocn. of van der Waals clusters of sulfur hexafluoride and argon in); Photolysis (laser-induced, of sulfur hexafluoride-argon van der Waals clusters, in sulfur isotope sepn.); Force (van der Waals, IR vibrational predissocn. of clusters of, in isotope sepn.); Energy level excitation (vibrational, laser-induced, in photodissocn. of van der Waals clusters of sulfur hexafluoride and argon, for isotope sepn.)
Laboratories:




 Record created 2011-02-01, last modified 2018-01-28


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