Abstract
The temp. jump relaxation method was used for kinetic measurements in the gas phase. The system N2O4 .dblarw. 2NO2 was studied. Fast temp. jumps were induced by IR absorption from a CO2 laser. Temp. jumps of <1 K led to readily detectable concn. changes which were monitored by UV absorption in a simple single shot expt. krec(Ar) is 1.05 * 1010 cm3-mol-1-s-1 at PAr = 1 bar and T = 258 K, in agreement with recent exptl. data.
Details
Title
Temperature jump measurements in gas kinetics
Author(s)
Gozel, P. ; Calpini, B. ; Van den Bergh, H.
Published in
Israel Journal of Chemistry
Volume
24
Issue
3
Pages
210-213
Date
1984
Keywords
Note
Copyright 2003 ACS
CAPLUS
AN 1985:87298
CAN 102:87298
73-10
Optical, Electron, and Mass Spectroscopy and Other Related Properties
67
Inst. Chim. Phys.,Ec. Polytech. Fed.,Lausanne,Switz. FIELD URL:
Journal
ISJCAT
written in English.
Laser radiation (in temp. jump relaxation method in study of nitrogen oxide-nitrogen tetroxide equil.); Optical absorption (UV, of nitrogen dioxide-nitrogen tetroxide system, temp. jump relaxation method in relation to)
CAPLUS
AN 1985:87298
CAN 102:87298
73-10
Optical, Electron, and Mass Spectroscopy and Other Related Properties
67
Inst. Chim. Phys.,Ec. Polytech. Fed.,Lausanne,Switz. FIELD URL:
Journal
ISJCAT
written in English.
Laser radiation (in temp. jump relaxation method in study of nitrogen oxide-nitrogen tetroxide equil.); Optical absorption (UV, of nitrogen dioxide-nitrogen tetroxide system, temp. jump relaxation method in relation to)
Laboratories
LPAS
Record Appears in
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Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Record creation date
2011-02-01