Temperature jump measurements in gas kinetics

The temp. jump relaxation method was used for kinetic measurements in the gas phase. The system N2O4 .dblarw. 2NO2 was studied. Fast temp. jumps were induced by IR absorption from a CO2 laser. Temp. jumps of <1 K led to readily detectable concn. changes which were monitored by UV absorption in a simple single shot expt. krec(Ar) is 1.05 * 1010 cm3-mol-1-s-1 at PAr = 1 bar and T = 258 K, in agreement with recent exptl. data.


Published in:
Israel Journal of Chemistry, 24, 3, 210-213
Year:
1984
Keywords:
Note:
Copyright 2003 ACS
CAPLUS
AN 1985:87298
CAN 102:87298
73-10
Optical, Electron, and Mass Spectroscopy and Other Related Properties
67
Inst. Chim. Phys.,Ec. Polytech. Fed.,Lausanne,Switz. FIELD URL:
Journal
ISJCAT
written in English.
Laser radiation (in temp. jump relaxation method in study of nitrogen oxide-nitrogen tetroxide equil.); Optical absorption (UV, of nitrogen dioxide-nitrogen tetroxide system, temp. jump relaxation method in relation to)
Laboratories:




 Record created 2011-02-01, last modified 2018-01-28


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