The photolytic cage effect of iodine in gases and liquids
The photolytic cage effect was studied over a wide d. range of several bath gases in the laser flash photolysis of I2 at 694.3 nm. Particular attention was paid to measurements in the simple solvents Xe and Kr, which were compared with mol. dynamics calcns. Measurements in polyat. gases and liqs. were made, as well as the variation of the cage effect with temp. and applied magnetic field. While measuring the cage effect under a wide variety of conditions, the second order rate consts. for I atom combination were also obtained.
Keywords: 14362-44-8P Role: RCT (Reactant) ; PREP (Preparation) ; RACT (Reactant or reagent) (formation and recombination of ; in photolysis of iodine in gases and liqs. ; cage effect in); 540-84-1 Role: USES (Uses) (photolysis of iodine in gas mixt. contg. ; cage eff ; iodine photolysis cage effect; gas iodine photolysis cage effect
Copyright 2003 ACS
Radiation Chemistry, Photochemistry, and Photographic and Other Reprographic Processes
Inst. Chim. Phys.,Swiss Fed. Inst. Technol.,Lausanne,Switz. FIELD URL:
written in English.
Photolysis (laser-induced, of iodine, in gases and liqs., cage effect in)
Record created on 2011-02-01, modified on 2016-08-09