Collisional energy transfer from excited polyatomic molecules produced by infrared multiple photon absorption
A simple energy-grained master equation was used to model data on the multiphoton dissocn. of CF2HCl as a function of laser fluence and Ar bath-gas pressure. Information on energy transfer from vibrationally excited CF2HCl was obtained from an anal. of the competition between laser pumping and collisional energy removal using suitable parametrizations of the laser intensity and the collision process.
Keywords: 75-45-6 Role: USES (Uses) (IR multiphoton dissocn. of ; collisional energy transfer in relation to) ; laser multiphoton dissocn chlorofluoromethane ; methane chlorodifluoro IR multiphoton absorption ; collisional energy transfer multiphoton absorption
Copyright 2003 ACS
Radiation Chemistry, Photochemistry, and Photographic Processes
Dep. Chem. Kinet.,SRI Int.,Menlo Park,CA,USA. FIELD URL:
written in English.
Laser radiation (absorption of many photons of, collisional energy transfer in relation to); Photon (absorption of many, by polyat. mols., collisional energy transfer in relation to); Photolysis (of chlorodifluoromethane, collisional energy transfer in relation to IR multiphoton-induced); Energy transfer (collisional, from polyat. mols. produced by IR multiphoton absorption)
Record created on 2011-02-01, modified on 2016-08-09