An investigation of laser intensity and temperature effects in the time-resolved infrared multiphoton dissociation of chlorodifluoromethane

The abs. :CF2 concn. is measured in situ and in real time by UV-absorption spectroscopy in the IR multiphoton dissocn. of CF2HCl during and after the laser pulse. The :CF2 prodn. rate is measured as a function of the laser intensity and the temp. at 9.17 mm. This rate increases with the IR intensity and temp. for nearly the whole range of conditions applied. At the highest temps. attained the :CF2 prodn. rates start to decrease with increasing temp.


Published in:
Journal of Molecular Structure, 61, 291-298
Year:
1980
Keywords:
Note:
Copyright 2003 ACS
CAPLUS
AN 1980:470686
CAN 93:70686
22-8
Physical Organic Chemistry
Inst. Chim. Phys.,Swiss Fed. Inst. Technol.,Lausanne,Switz. FIELD URL:
Journal
JMOSB4
written in English.
Photolysis (IR laser-induced, of chlorodifluoromethane, multiphoton)
Laboratories:




 Record created 2011-02-01, last modified 2018-01-28


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