Time-resolved measurement of difluoromethylene radical formation in the infrared multiphoton dissociation of chlorodifluoromethane
Duperrex, R.; Van den Bergh, H.
1979

Abstract

The IR multiphonon dissocn. of CF2HCl was investigated by monitoring the appearance of the CF2 product in real time during and after the laser pulse. The difluorcarbene radicals were detected quant. by their optical absorption in the ~A1B1->~X1A1 band system around 250 nm. The fragmentation was studied under collision-free conditions as well as in the presence of up to 500 torr Ar.

Details

Title Time-resolved measurement of difluoromethylene radical formation in the infrared multiphoton dissociation of chlorodifluoromethane
Author(s) Duperrex, R. ; Van den Bergh, H.
Published in Journal of Chemical Physics
Volume 71
Issue 9
Pages 3613
Date 1979
Keywords
Note Copyright 2003 ACS
CAPLUS
AN 1980:119620
CAN 92:119620
74-1
Radiation Chemistry, Photochemistry, and Photographic Processes
73
Inst. Chim. Phys.,Ec. Polytech. Fed.,Lausanne,Switz. FIELD URL:
Journal
JCPSA6
written in English.
Photolysis (IR, laser-induced, multiphoton, of chlorodifluoromethane, difluoromethylene radical formation in, time-resolved measurement of)
DOI https://doi.org/10.1063/1.438820
Laboratories LPAS
Record Appears in Scientific production and competences > ENAC - School of Architecture, Civil and Environmental Engineering > ENAC Archives > LPAS - Air and Soil Pollution Laboratory
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Record creation date 2011-02-01

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