Time-resolved measurement of difluoromethylene radical formation in the infrared multiphoton dissociation of chlorodifluoromethane

The IR multiphonon dissocn. of CF2HCl was investigated by monitoring the appearance of the CF2 product in real time during and after the laser pulse. The difluorcarbene radicals were detected quant. by their optical absorption in the ~A1B1->~X1A1 band system around 250 nm. The fragmentation was studied under collision-free conditions as well as in the presence of up to 500 torr Ar.


Published in:
Journal of Chemical Physics, 71, 9, 3613
Year:
1979
Keywords:
Note:
Copyright 2003 ACS
CAPLUS
AN 1980:119620
CAN 92:119620
74-1
Radiation Chemistry, Photochemistry, and Photographic Processes
73
Inst. Chim. Phys.,Ec. Polytech. Fed.,Lausanne,Switz. FIELD URL:
Journal
JCPSA6
written in English.
Photolysis (IR, laser-induced, multiphoton, of chlorodifluoromethane, difluoromethylene radical formation in, time-resolved measurement of)
Laboratories:




 Record created 2011-02-01, last modified 2018-01-28


Rate this document:

Rate this document:
1
2
3
 
(Not yet reviewed)