Rate consts. for the recombination of Me radicals in the low-pressure limit were calcd. at 300-1400 K, along with the isotope effect for perdeutero substitution. The calcd. low-pressure rate consts. were substantiated by data extrapolated from expts. in the fall-off range.
Title
The recombination of methyl radicals in the low pressure limit
Published in
Chemical Physics Letters
Volume
43
Issue
2
Pages
201-204
Date
1976
Note
Copyright 2003 ACS
CAPLUS
AN 1977:88750
CAN 86:88750
22-4
Physical Organic Chemistry
Inst. Chim. Phys.,Ec. Polytech. Fed. Lausanne,Lausanne,Switz. FIELD URL:
Journal
CHPLBC
written in English.
Kinetics of recombination (of methyl radical, at low pressure in argon and in helium)
Record creation date
2011-02-01