Nitrogen oxide-catalyzed recombination of iodine atoms. Elementary steps of the complex mechanism

Van den Bergh, H.; Troe, J.

doi:10.1016/0009-2614(75)85038-X

Van den Bergh, H.; Troe, J.

1975

Formats

Format
BibTeX
MARC
MARCXML
DublinCore
EndNote
NLM
RefWorks
RIS

Abstract

The recombination of I atoms in the presence of NO was studied by laser flash photolysis in the inert gas He, at pressures between 1 and 200 atm and at temps. from 320-440 DegK. The elementary steps of the complex mechanism of the recombination were resolved. The fall-off curve of the interaction I + NO + He -> INO + He was measured as well as the equil. const. for I + NO .tautm. INO. The bond energy of INO is DH00 = 23 +- 3 kcal mole-1.

Details

Title Nitrogen oxide-catalyzed recombination of iodine atoms. Elementary steps of the complex mechanism

Author(s) Van den Bergh, H. ; Troe, J.

Published in Chemical Physics Letters

Volume 31

Issue 2

Pages 351-354

Date 1975

Keywords

10102-43-9 Role: CAT (Catalyst use); USES (Uses) (catalysis by; of iodine atom recombination); 14362-44-8 Role: RCT (Reactant); RACT (Reactant or reagent) (recombination of; nitric oxide catalysis of); nitric oxide catalysis iodine recombination

Note Copyright 2003 ACS
CAPLUS
AN 1975:175753
CAN 82:175753
67-2
Catalysis and Reaction Kinetics
Inst. Chim. Phys.,Ec. Polytech. Fed.,Lausanne,Switz. FIELD URL:
Journal
CHPLBC
written in English.
Recombination catalysts (nitric oxide, for iodine atoms); Recombination (of iodine atoms, mechanism of nitric oxide-catalyzed); Kinetics of recombination (of iodine atoms, with nitric oxide catalysis)

DOI https://doi.org/10.1016/0009-2614(75)85038-X

Laboratories LPAS

Record Appears in Scientific production and competences > ENAC - School of Architecture, Civil and Environmental Engineering > ENAC Archives > LPAS - Air and Soil Pollution Laboratory
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published

Record creation date 2011-02-01

Abstract

Details

Actions