Spectroscopic measurement of the rate of the gas-phase combination of methyl radicals with nitric oxide and oxygen at 295.deg.K
Van den Bergh, H. E.; Callear, A. B.
1971

Résumé

The rates of combination of Me. with NO and O2 were measured by flash spectroscopy at 295 DegK. The highpressure rate coeff. for Me. + NO(+M) -> MeNO(+M) was recorded as 1.0(+-0.15) * 1013 cm3 mole-1 sec-1. The low-pressure fall-off was interpreted with the Rice-Marcus model for D0(Me-NO) = 46.8kcal mole-1. The high-pressure rate coeff. for Me + O2(+M) -> MeO2(+M) was deduced to be .apprx.1.1 * 1012 cm3 mole-1 sec-1.

Détails

Titre Spectroscopic measurement of the rate of the gas-phase combination of methyl radicals with nitric oxide and oxygen at 295.deg.K
Auteur(s) Van den Bergh, H. E. ; Callear, A. B.
Publié dans Transactions of the Faraday Society
Volume 67
Numéro 7
Pages 2017-2024
Date 1971
Mots-clés (libres)
Note CAPLUS
AN 1971:467935
CAN 75:67935
67
Catalysis and Reaction Kinetics
Phys. Chem. Lab.,Cambridge,UK. FIELD URL:
TFSOA4
Bonds (energy of, carbon-nitrogen in nitroso methane); Kinetics (of methyl radicals, with nitrogen oxide and oxygen)
DOI https://doi.org/10.1039/tf9716702017
Laboratoires LPAS
Le document apparaît dans Production scientifique et compétences > ENAC - Faculté de l'environnement naturel, architectural et construit > ENAC Archives > LPAS - Laboratoire de pollution atmosphérique et du sol
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Travail hors EPFL
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Publié
Date de création de la notice 2011-02-01

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