Experimental determination of the oscillator strength of the B(2B1)-X(2A2) transition of the free allyl radical
1970
Abstract
The integrated absorption of the b1 - X transition of the Me radical (2160 .ANG.) and the B - X transition of the allyl radical (2100-2400 .ANG.) were compared, in the flash photolysis of 1-butene. From the f value of the Me band, the oscillator strength of the allyl transition was recorded as 0.140 (+-0.028). The rate coeff. for recombination of allyl radicals was in the range 8.5(+-3) * 1012 cm3 mole-1 sec-1.
Details
Title
Experimental determination of the oscillator strength of the B(2B1)-X(2A2) transition of the free allyl radical
Author(s)
Van den Bergh, H. E. ; Callear, Anthony B.
Published in
Transactions of the Faraday Society
Volume
66
Pages
2681-2684
Date
1970
Keywords
Note
Copyright 2003 ACS
CAPLUS
AN 1970:535618
CAN 73:135618
73
Spectra by Absorption, Emission, Reflection, or Magnetic Resonance, and Other Optical Properties
Phys. Chem. Lab.,Cambridge,UK. FIELD URL:
Journal
TFSOA4
written in English.
Spectra (of allyl and methyl radicals, oscillator strengths of lines in); Kinetics of recombination (of allyl radicals); Photolysis (of butene)
CAPLUS
AN 1970:535618
CAN 73:135618
73
Spectra by Absorption, Emission, Reflection, or Magnetic Resonance, and Other Optical Properties
Phys. Chem. Lab.,Cambridge,UK. FIELD URL:
Journal
TFSOA4
written in English.
Spectra (of allyl and methyl radicals, oscillator strengths of lines in); Kinetics of recombination (of allyl radicals); Photolysis (of butene)
Laboratories
LPAS
Record Appears in
Scientific production and competences > ENAC - School of Architecture, Civil and Environmental Engineering > ENAC Archives > LPAS - Air and Soil Pollution Laboratory
Peer-reviewed publications
Work outside EPFL
Journal Articles
Published
Peer-reviewed publications
Work outside EPFL
Journal Articles
Published
Record creation date
2011-02-01