On the absorption spectrum and stability of Ag32+ in aqueous solution

Pulse radiolysis results suggest that the very first steps of silver aggregation in water involve the formation of Ag32+. The authors present a mixed classical quantum simulation of the absorption spectrum of this aggregate which is in agreement with the exptl. spectrum. The formation and structure of this aggregate are discussed with the help of addnl. Monte Carlo and ab initio calcns. The results tend to confirm the formation of Ag32+.


Published in:
Chemical Physics Letters, 389, 1-3, 150-154
Year:
2004
Publisher:
Elsevier
ISSN:
0009-2614
Keywords:
Laboratories:




 Record created 2011-01-25, last modified 2018-03-17

n/a:
Download fulltext
PDF

Rate this document:

Rate this document:
1
2
3
 
(Not yet reviewed)