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Brillouin scattering is particularly efficient and attractive for the implementation of strain and temperature distributed sensing in optical fibres. Recently a trend has been observed that modern advanced applications require a substantial step towards better spatial resolution, while preserving temperature/strain precision over a long range. For this purpose the state of the art does not satisfy all these requirements. In this thesis we present a radically new approach named Brillouin Echoes distributed sensing (BEDS) that allows covering these requirements. In the first part, we propose an updated configuration of the classical existing Brillouin sensor for time domain analysis allowing drastic noise reduction. Then we investigate the limitations (due to non-linear effects) of the classical Brillouin sensor in terms of long distance range measurements. The identified nonlinear effects are pump depletion due to SBS itself, self-phase modulation (SPM), modulation instability (MI), which occurs only in fibres presenting an anomalous dispersion at the pump wavelength and Raman scattering (RS). We propose the modeling of the pump depletion effect to obtain analytical expressions that are useful for the proper design of a BOTDA sensor and for the determination of a very small depletion. The model confirmed by experimental measurements is informative on the conditions maximizing the depletion effect; therefore a standard configuration can be defined to test the value of the depletion in the set-up. Furthermore, we demonstrate that SPM-induced spectral broadening can have a significant effect on the measured effective gain linewidth. Modeling and experiments have undoubtedly demonstrated that the effective gain linewidth can easily experience a two-fold increase in standard conditions when the pulse intensity profile is Gaussian. We showed that the problem can be practically circumvented by using a clean rectangular pulse with very sharp rising and falling edges. The theoretical and experimental analysis of the undesirable effects of MI and forward RS in distributed BOTDA sensors systems gives a simplified expression to predict the critical power for a given distance range. MI turns out to be the dominant nonlinear limitation since it shows the lowest critical power, but it is less critical since it can be avoided to a wide extent by using the fibre in the normal dispersion spectral region such as a DSF in the C-band. On the other hand Raman scattering can be avoided only by limiting the optical pump power and therefore is the ultimate nonlinear limitation in a distributed sensing system. Under similar conditions RS shows a critical power ∼5 times larger than MI. In the second part, we present the new approach Brillouin echo distributed sensing (BEDS) which has proved to be a powerful solution to realize sub-metric spatial resolutions in Brillouin distributed measurements. We have demonstrated both theoretically and experimentally that an optimized configuration is reached when the optical wave is π-phase shifted. The experimental tests have shown a spatial resolution down to 5 cm, with a clear margin for further improvement down to a real centimetric spatial resolution. This optimized configuration produce the best contrast independently of the pulse intensity, with a factor 2 of improvement compared to other techniques based on the same approach (dark pulse, bright pulse). This extends the dynamic range by 3 dB, which corresponds in standard loss conditions to a 5 km extension of the sensing range. An analytical developed model has proved to be an excellent tool not only for optimizing the pumping scheme but also in post-processing the measured data. Finally the potentialities of BEDS technology provide solutions in real contexts. Using the BEDS technology in landslide monitoring at laboratory scale, for the first time it became possible to observe the failure propagation in laboratory scale with an accurate precision. Furthermore, using BEDS we have proposed and demonstrated the possibility of mapping geometrical structure fluctuations along a photonic crystal fibre (PCF). Both long- and short-scale longitudinal fluctuations in the Brillouin frequency shift have been identify and quantify. Observation of Brillouin linewidth broadening in PCF fibre through distributed measurement of the Brillouin gain spectrum using BEDS has allowed fundamental understanding of SBS in PCF fibre and in their design in view of applications to optical-strain/temperature sensing.