000161928 001__ 161928
000161928 005__ 20180925134131.0
000161928 022__ $$a1359-7345
000161928 0247_ $$2doi$$a10.1039/C0CC02265A
000161928 037__ $$aARTICLE
000161928 245__ $$aBenziodoxole-based hypervalent iodine reagents for atom-transfer reactions
000161928 269__ $$a2011
000161928 260__ $$c2011
000161928 336__ $$aReviews
000161928 520__ $$aIn the last decades, hypervalent iodine reagents have raised from chemical curiosities to mainstream reagents in organic synthesis. The use of benziodoxole-derived reagents has been especially successful in oxidation methods, whereas non-cyclic iodinanes have been used both for oxidation and atom-transfer reactions. On the other hand, the exceptional properties of benziodoxole reagents for atom-transfer reactions have only started to attract the attention of the synthetic community more recently. In this review, progress in the use of these compounds for C–X and C–C bond formations will be presented. In particular, recent breakthroughs in trifluoromethylation and alkynylation reactions have been realized since 2006 based on benziodoxole-derived reagents and these results are the main focus of this article.
000161928 700__ $$0243585$$aBrand, Jonathan P.$$g183304
000161928 700__ $$0243587$$aFernandez Gonzalez, Davinia$$g167685
000161928 700__ $$0243588$$aNicolai, Stefano$$g188505
000161928 700__ $$0243584$$aWaser, Jérôme$$g181574
000161928 773__ $$j47$$q102-115$$tChemical Communications- Royal Society of Chemistry
000161928 8560_ $$fjerome.waser@epfl.ch
000161928 8564_ $$s1679807$$uhttps://infoscience.epfl.ch/record/161928/files/CC2011-102GreenAccess.pdf
000161928 909C0 $$0252236$$pLCSO$$xU11811
000161928 909CO $$ooai:infoscience.tind.io:161928$$pSB$$particle$$qreview
000161928 917Z8 $$x181574
000161928 937__ $$aEPFL-REVIEW-161928
000161928 973__ $$aEPFL$$rREVIEWED$$sPUBLISHED
000161928 980__ $$aARTICLE