Synthesis of new aminophosphine complexes and their catalytic activities in C-C coupling reactions
Two new aminophosphines, benzyl-N(Ph2P)(2) and 2-picolyl-N(Ph2P)(2), have been synthesized. Oxidation of the aminophosphines with either hydrogen peroxide, elemental sulfur and selenium gave the corresponding oxides, sulfides and selenides benzyl-N(Ph2P=E)(2) and 2-picolyl-N(Ph2P=E)(2), where E = O, S, or Se. Complexes [benzyl-N(Ph2P)(2)]MCl2 and [2-picolyl-N(Ph2P)(2)]MCl2, where M = Pd, Pt, were obtained by the reaction of the aminophosphines with MCl2(cod). The new compounds were characterised by NMR, IR spectroscopy and microanalysis. Furthermore, representative solid-state structures of the palladium and platinum complexes were determined using single crystal X-ray diffraction analysis. The palladium complexes were further investigated as potential catalysts in C-C coupling reactions. (c) 2008 Elsevier B. V. All rights reserved.
Keywords: aminophosphine ; synthesis ; oxidation ; X-ray structures ; catalysis ; X-Ray-Structure ; 2 1,3,2-Benzodiazaphosphorinone Units ; Ligands (Ph2P)(2)Nh Dppa ; Mixed-Metal Clusters ; Coordination Chemistry ; Phosphinoamide Anion ; Oxidation ; Derivatives ; Reactivity ; Crystal
Record created on 2010-11-30, modified on 2016-08-09