Approach towards the total synthesis of cyclopeptide alkaloids

Macrocylization via formation of the aryl-alkyl ether bond was a key step in a model synthesis of 14-membered cyclopeptide alkaloids. A new chemoenzymic synthesis of chiral 2-amino-1-arylethanol was developed in the course of this study. [on SciFinder (R)]


Published in:
Tetrahedron Letters, 39, 3/4, 283-286
Year:
1998
Keywords:
Note:
CAN 128:141009
34-3
Amino Acids, Peptides, and Proteins
Institut de Chimie des Substances Naturelles, CNRS,Gif-sur-Yvette,Fr.
Journal
0040-4039
written in English.
202120-58-9P; 202120-59-0P Role: BPN (Biosynthetic preparation), BIOL (Biological study), PREP (Preparation) (approach towards total synthesis of cyclopeptide alkaloids); 202120-60-3P; 202120-61-4P; 202134-17-6P; 202134-18-7P; 202134-19-8P; 202217-47-8P; 202217-48-9P; 202217-49-0P Role: BPN (Biosynthetic preparation), RCT (Reactant), SPN (Synthetic preparation), BIOL (Biological study), PREP (Preparation), RACT (Reactant or reagent) (approach towards total synthesis of cyclopeptide alkaloids); 202120-54-5P Role: BPN (Biosynthetic preparation), SPN (Synthetic preparation), BIOL (Biological study), PREP (Preparation) (approach towards total synthesis of cyclopeptide alkaloids); 202120-62-5P Role: BYP (Byproduct), PREP (Preparation) (approach towards total synthesis of cyclopeptide alkaloids); 202120-57-8P Role: PUR (Purification or recovery), RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (approach towards total synthesis of cyclopeptide alkaloids); 13139-15-6; 42564-51-2; 93527-55-0 Role: RCT (Reactant), RACT (Reactant or reagent) (approach towards total synthesis of cyclopeptide alkaloids); 202120-55-6P; 202120-56-7P; 202120-63-6P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (approach towards total synthesis of cyclopeptide alkaloids)
Laboratories:




 Record created 2010-11-25, last modified 2018-09-13


Rate this document:

Rate this document:
1
2
3
 
(Not yet reviewed)