000158065 001__ 158065
000158065 005__ 20181203022128.0
000158065 0247_ $$2doi$$a10.1002/anie.200704840
000158065 037__ $$aARTICLE
000158065 245__ $$aSynthesis of alpha -keto amides by a molecular-sieves-promoted formal oxidative coupling of aliphatic aldehydes with isocyanides
000158065 269__ $$a2008
000158065 260__ $$c2008
000158065 336__ $$aJournal Articles
000158065 500__ $$aCAN 148:402630
000158065 500__ $$a21-2
000158065 500__ $$aGeneral Organic Chemistry
000158065 500__ $$aInstitut de Chimie de Substances Naturelles,CNRS,Gif-sue-Yvette Cedex,Fr.
000158065 500__ $$aJournal
000158065 500__ $$a1433-7851
000158065 500__ $$awritten in English.
000158065 500__ $$a64-19-7 (Acetic acid); 104-53-0 (Benzenepropanal); 111-71-7 (Heptanal); 931-53-3 (Cyclohexyl isocyanide); 1930-94-5; 4229-44-1 (N-Methylhydroxylamine hydrochloride); 5949-05-3 ((S)-Citronellal); 7188-38-7 (tert.-Butyl isocyanide); 10340-91-7 (Benzyl isocyanide); 29601-98-7 (N-Benzylhydroxylamine hydrochloride); 33904-01-7 (3,4-Dimethoxyphenyl isocyanide); 39687-95-1 (Methyl isocyanoacetate); 57497-39-9 (N-tert.-Butylhydroxylamine hydrochloride); 63157-14-2; 66251-86-3; 98648-05-6; 107201-33-2; 1015255-66-9 Role: RCT (Reactant), RACT (Reactant or reagent) (synthesis of alpha -keto amides by a mol.-sieves-promoted formal oxidative coupling of aliph. aldehydes with isocyanides); 66251-87-4P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (synthesis of alpha -keto amides by a mol.-sieves-promoted formal oxidative coupling of aliph. aldehydes with isocyanides); 34633-21-1P; 66251-88-5P; 76399-69-4P; 345922-07-8P; 629648-27-7P; 1015255-63-6P; 1015255-64-7P; 1015255-65-8P; 1015255-67-0P; 1015255-68-1P; 1015255-69-2P; 1015255-70-5P; 1015255-71-6P; 1015255-72-7P; 1015255-73-8P; 1015255-74-9P; 1015255-75-0P; 1015255-76-1P Role: SPN (Synthetic preparation), PREP (Preparation) (synthesis of alpha -keto amides by a mol.-sieves-promoted formal oxidative coupling of aliph. aldehydes with isocyanides)
000158065 520__ $$aThe reaction of an aldehyde, an isocyanide, N-methylhydroxylamine, and acetic acid in the presence of 4-.ANG. mol. sieves afforded alpha -keto amides in moderate to good yields. In contrast, 3-.ANG. mol. sieves did not promote the desired multicomponent reaction. [on SciFinder (R)]
000158065 6531_ $$aAmides Role: SPN (Synthetic preparation)
000158065 6531_ $$aPREP (Preparation) (oxo; synthesis of alpha -keto amides by a mol.-sieves-promoted formal oxidative coupling of aliph. aldehydes with isocyanides); Coupling reaction; Molecular sieves (synthesis of alpha -keto amides by a mol.-sieves-promoted formal oxidative coupling of aliph. aldehydes with isocyanides); Aldehydes; Isocyanides Role: RCT (Reactant)
000158065 6531_ $$aRACT (Reactant or reagent) (synthesis of alpha -keto amides by a mol.-sieves-promoted formal oxidative coupling of aliph. aldehydes with isocyanides)
000158065 6531_ $$aketo amide prepn four component mol sieves catalyst
000158065 700__ $$aGrassot, Jean-Marie
000158065 700__ $$aMasson, Geraldine
000158065 700__ $$0244710$$aZhu, Jieping$$g206332
000158065 773__ $$j47$$k5$$q947-950$$tAngewandte Chemie, International Edition
000158065 909C0 $$0252341$$pLSPN$$xU12326
000158065 909CO $$ooai:infoscience.tind.io:158065$$pSB$$particle
000158065 937__ $$aEPFL-ARTICLE-158065
000158065 973__ $$aOTHER$$rREVIEWED$$sPUBLISHED
000158065 980__ $$aARTICLE