Infoscience

Journal article

Low-power decoupling at high spinning frequencies in high static fields

We demonstrate that heteronuclear decoupling using a Phase-Inverted Supercycled Sequence for Attenuation of Rotary Resonance (PISSARRO) is very efficient at high spinning frequencies (v(rot) = 60 kHz) and high magnetic fields (900 MHz for protons at 21 T) even with moderate radio-frequency decoupling amplitudes (v(1)' = 15 kHz), despite the wide range of isotropic chemical shifts of the protons and the increased effect of their chemical shift anisotropy. (C) 2009 Elsevier Inc. All rights reserved.

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