Broadband magnetization transfer using moderate radio-frequency fields for NMR with very high static fields and spinning speeds

We introduce a new dipolar recoupling scheme, dubbed PARIS-xy (phase-alternated recoupling irradiation scheme using orthogonal radio-frequency phases), to promote efficient broadband magnetization exchange between C-13 nuclei using moderate radio-frequency amplitudes at very high magnetic field strengths and spinning speeds. Experimental observations for a wide range of spinning frequencies 30 <= nu(rot) <= 60 kHz and magnetic field strengths (B-0 = 9.4, 17.6 and 21.2 T) are backed up by numerical simulations. (C) 2010 Elsevier B. V. All rights reserved.


Published in:
Chemical Physics Letters, 488, 10-16
Year:
2010
Publisher:
Elsevier
ISSN:
0009-2614
Keywords:
Laboratories:




 Record created 2010-06-03, last modified 2018-03-17


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