Fast Ion-Transfer Processes at Nanoscopic Liquid/Liquid Interfaces

Keeping up: The fastest kinetic data for ion transfer at a liquid/liquid interface were evaluated by nanopipette voltammetry. The steady-state voltammograms can be explained by theoretical models. In previous electrochemical measurements the systematic underestimation of k0 is probably a result of inefficient mass transfer to the relatively large interface.


Published in:
Angewandte Chemie, International Edition, 48, 43, 8010-8013
Year:
2009
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