Fast Ion-Transfer Processes at Nanoscopic Liquid/Liquid Interfaces
Keeping up: The fastest kinetic data for ion transfer at a liquid/liquid interface were evaluated by nanopipette voltammetry. The steady-state voltammograms can be explained by theoretical models. In previous electrochemical measurements the systematic underestimation of k0 is probably a result of inefficient mass transfer to the relatively large interface.
Keywords: cyclic voltammetry ; kinetics ; interfaces ; ion transfer ; nanopipettes ; Liquid-Liquid Interface ; Scanning Electrochemical Microscopy ; Steady-State Voltammograms ; Potassium-Ion ; Dibenzo-18-Crown-6 ; Kinetics ; Micropipette ; Voltammetry ; Solvation ; Ities
Record created on 2010-01-06, modified on 2016-08-08