Theoretical treatment and computer simulation of microelectrode arrays

New relations for and interrelations between the current responses of different microelectrode arrays are presented. Interdigitated microelectrode arrays (IDAs: alternating cathodes and anodes) and uniform microband electrode arrays (MEAs: only cathodes or anodes) are treated, and miniaturized systems with planar band electrodes or hemicylinder electrodes are discussed. A common basis was found for the specific response characteristics of IDAs and MEAs. The theoretical expressions were verified by results from computer modelling. The numerical simulations made use of finite-element procedures to evaluate steady-state and time-dependent mass fluxes and concentration profiles of electroactive species at the surfaces of different microelectrode arrays. It was shown that the response behavior of a given array can be exactly predicted from the current data of other arrays. © 2006 Elsevier B.V. All rights reserved.


Published in:
Journal of Electroanalytical Chemistry, 590, 1, 47-56
Year:
2006
ISSN:
00220728
Note:
369
Laboratories:




 Record created 2009-05-12, last modified 2018-03-17


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