Neutral ligands with exceptional donor ability for palladium-catalyzed alkene hydrogenation

With four site: Catalytic olefin hydrogenation is observed with palladium complexes when the N-heterocyclic carbene ligand is changed from the normal C2- to the unusual C4-bonding mode (see scheme). In a cis coordinating framework, the electron density at the metal center is substantially increased as a result of the exceptionally strong donor ability of C4-bound carbenes. (Chemical Equation Presented) © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.


Published in:
Angewandte Chemie International, 46, 6293-6296
Year:
2007
Note:
421
Other identifiers:
Scopus: 2-s2.0-34548216695
Laboratories:




 Record created 2009-05-12, last modified 2018-01-28


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