An Original Redox-Responsive Ligand Based on a Extended TTF Framework

The synthesis of the first π-extended tetrathiafulvalene (TTF) ligand featuring a furanoquinonoid spacer and pyridyl functional groups is described. This compound shows an unprecedented electrochemical sensing behavior and excellent coordinating properties toward selected divalent metal ions. Solid-state structures of the free ligand and its Ni(II)Cl2 complex are described. © 2007 American Chemical Society.


Published in:
Organic Letters, 9, 19, 3753-3756
Year:
2007
ISSN:
15237060
Note:
423
Other identifiers:
Scopus: 2-s2.0-34848843758
Laboratories:




 Record created 2009-05-12, last modified 2018-03-17


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